Organotitanium Fluorides as Matrices for Trapping Molecular ZnF(2) and MeZnF.
نویسندگان
چکیده
Trapped as molecular solids, the transition metal fluorides ZnF(2) and MeZnF-the latter isolated for the first time-exist as adducts in [(Cp*TiF(3))(8)(ZnF(2))(3)] (1) and [(Cp*TiF(3))(4)(MeZnF)(2)] (2), respectively. Compounds 1 and 2 were obtained in reactions of [Cp*TiF(3)] (Cp*=C(5)Me(5)) with ZnMe(2) and Me(3)SnF in various molar ratios. The single-crystal structure of 1 is shown here; the unlabeled circles are F atoms.
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 38 22 شماره
صفحات -
تاریخ انتشار 1999